Reduction of pollutants in pulp paper mill effluent treated by PCP-degrading bacterial strains

Two PCP-degrading bacterial strains, Bacillus cereus (ITRC-S6) and Serratia marcescens (ITRC-S7) were used for the treatment of pulp and paper mill effluent at conditions; 1.0% glucose and 0.5% peptone at 30 +/- 1 degrees C at 120 rpm for 168 h of incubation. These two bacterial strains effectively reduced colour (45-52%), lignin (30-42%), BOD (40-70%), COD (50-60%), total phenol (32-40%) and PCP (85-90%) within 168 h of incubation. However, the highest reduction in colour (62%), lignin (54%), BOD (70%), COD (90%), total phenol (90%) and PCP (100%) was recorded by mixed culture treatment. The bacterial mechanism for the degradation of pulp and paper mill effluent may be explained by an increase in the cells biomass using added co-substrates resulting liberation of significant amount of chloride due to bacterial dechlorination of chlorolignins and chlorophenols this showed reduction in colour, lignin and toxicity in the effluent. Further, GC-MS analysis of ethyl acetate-extractable compounds from treated pulp paper mill effluent reinforces the bacterium capability for the degradation of lignin and pentachlorophenol, as many aromatic compounds such as 2-chlorophenol, 2, 4, 6-trichlorophenol and tetrachlorohydroquinone, 6-chlorohydroxyquinol and tetrachlorohydroquinone detected which were not present in the untreated effluent.     

Study on the removal of NOx from simulated flue gas using acidic NaClO2 solution

The study on the removal of NOx from simulated flue gas has been carded out in a lab-scale bubbling reactor using acidic solutions of sodium chlorite. Experiments were performed at various pH values and inlet NO concentrations in the absence or presence of SO2 gas at 45℃. The effect of SO2 on NO oxidation and NO2 absorption was critically examined. The oxidative ability of sodium chlorite was investigated at different pH values and it was found to be a better oxidant at a pH less than 4. In acidic medium, sodium chlorite decomposed into C102 gas, which is believed to participate in NO oxidation as well as in NO2 absorption. A plausible NOx removal mechanism using acidic sodium chlorite solution has been postulated. A maximum NOx removal efficiency of about 81% has been achieved.     

Remote sensing of atmospheric aerosol in the nocturnal boundary layer using lidar

This paper presents the results of the lidar experiments that have been performed during January 1989 through August 1990 to study the aerosol vertical distributions in the nocturnal atmosphere and their comparison with near-simultaneous aerological soundings for environmental monitoring. During the study period, the aerosol distributions showed significant stratified aerosol layer structures in the lower atmosphere throughout the south-west monsoon season (June-September), while these structures appear to be either erratic or absent during remaining months of the year. In addition, the aerosols present in the lowest air layers up to 200 m are found to contribute significantly (about 40%) to the aerosol loading in the nocturnal boundary layer at the lidar site. The pre-monsoon to winter ratio of mixing depth and ventilation coefficient were found to be 1.11 and 1.62, respectively. Thus the height of the mixed layer (around 350 m) and the associated ventilation coefficients suggest that early winter evenings tend to have higher pollution potential at the experimental site. The results indicate that the lidar technique has the potential to yield good information on the structure of the nocturnal atmosphere which is found to be influenced by the atmospheric stability conditions as revealed by aerological observations.     

Diversity of ground arthropod community at organic and chemically intensive tea plantation of Darjeeling terai

Tea in Darjeeling foothills and terai are grown conventionally, with application of chemical fertilizers and pesticides, as well as organically without these inputs. Ground level arthropod community was collected from the above two types of tea plots using pitfall traps. Catches from these environments showed variation in the arthropod faunal structure with numerically and taxonomically greater abundance in the organic than that of the conventional plot. Coleopterans were more diverse with largest number of families and Recognizable Taxonomic Units (or morphospecies) in the organic tea plot. The diversity and similarity indices for coleopterans were comparable, in organic and conventional tea plots at species and family levels. The close relationship of the indices suggested that diversity study at family level could be used as surrogate for species level diversity; thus alleviating the laborious and expertise job of taxonomic identification of arthropod species. Faunal diversity study at ground level gave the clue that soil of the organic plantation was healthier than that of the conventional tea plot.     

Effect of pH and salinity on pathogenicity of Flavobacterium columnare and Myxobacterium sp. in Indian cat fish, Clarias batrachus (Linn.) and Heteropneustes fossilis (Bloch.)

Flavobacterium columnare (FC) and Myxobacterium sp. recorded persistently associated in fish hatchery and culture system of Himalayan and Sub - Himalayan regions were found to be pathogenic. The pH and salinity played a significant role on the pathogenicity of these potent pathogens in case of Clarias batrachus and Heteropneustes fossilis. LD50 value of FC was 10(4.5) CFU in both the fishes and those of Myxobacterium sp it was 10(6) CFU ml(-1) fish(-1). Fish challenged with F. columnare and Myxobacterium sp. (@ 0.2 ml fish(-1)) individually consisting 10(5-6) cfu ml(-1) exhibited explicit symptoms of columnaris disease and marked with ulceration and saddle back lesion on the dorsal side of body. Maximum reisolation of inoculated bacteria was recorded at pH 7.0 and 7.5 and at 0.0-0.5 (F. columnare) and 0.0-1.0% (Myxobacterium sp.) salinity. Foregoing results elucidated that F. columnare was more sensitive to salinity in comparison to Myxobacterium sp. and their pathogenicity significantly (p<0.05) depends on the salinity and pH that might be one of the physical factors to control their proliferation.     

Mass flows of perfluorinated compounds (PFCs) in central wastewater treatment plants of industrial zones in Thailand

Perfluorinated compounds (PFCs) are fully fluorinated organic compounds, which have been used in many industrial processes and have been detected in wastewater and sludge from municipal wastewater treatment plants (WWTPs) around the world. This study focused on the occurrences of PFCs and PFCs mass flows in the industrial wastewater treatment plants, which reported to be the important sources of PFCs. Surveys were conducted in central wastewater treatment plant in two industrial zones in Thailand. Samples were collected from influent, aeration tank, secondary clarifier effluent, effluent and sludge. The major purpose of this field study was to identify PFCs occurrences and mass flow during industrial WWTP. Solid-phase extraction (SPE) coupled with HPLC-ESI-MS/MS were used for the analysis. Total 10 PFCs including perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluoropropanoic acid (PFPA), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), perfluorohexane sulfonate (PFHxS), perfluoronanoic acid (PFNA), perfluordecanoic acid (PFDA), perfluoroundecanoic acid (PFUnA), and perfluorododecanoic acid (PFDoA) were measured to identify their occurrences. PFCs were detected in both liquid and solid phase in most samples. The exceptionally high level of PFCs was detected in the treatment plant of IZ1 and IZ2 ranging between 662-847 ng L⁻¹ and 674-1383 ng L⁻¹, respectively, which greater than PFCs found in most domestic wastewater. Due to PFCs non-biodegradable property, both WWTPs were found ineffective in removing PFCs using activated sludge processes. Bio-accumulation in sludge could be the major removal mechanism of PFCs in the process. The increasing amount of PFCs after activated sludge processes were identified which could be due to the degradation of PFCs precursors. PFCs concentration found in the effluent were very high comparing to those in river water of the area. Industrial activity could be the one of major sources of PFCs contamination in the water environment.     

Pre-concentration and separation of heavy metal ions by chemically modified waste paper gel

Iminodiacetic acid was immobilized on waste paper by chemical modification in order to develop a new type of adsorption gel for heavy metal ions. Adsorption behavior of the gel was investigated for a number of metal ions, specifically Cu(II), Pb(II), Fe(III), Ni(II), Cd(II), and Co(II) at acidic pH. From batch adsorption tests, the order of selectivity was found to be as follows: Cu(II)  Fe(III) > Pb(II) > Ni(II)  Co(II) > Cd(II). Column tests were carried out for pairs of metal ions to understand the separation and pre-concentration behavior of the gel. It was found that mutual separation of Ni(II) from Co(II) and that of Pb(II) from Cd(II) can be achieved at pH 3. Similarly, selective separation of Cu(II) from Cu(II)–Fe(III) and Cu(II)–Pb(II) mixtures at pH 1.5 and 2, respectively, was observed by using this new adsorption gel. In all cases, almost complete recovery of the adsorbed metal was confirmed by elution tests with HCl.     

Active biomonitoring with wet and dry moss: a case study in an urban area

Active biomonitoring of the air quality in Belgrade, Serbia, was performed using the moss Sphagnum girgensohnii. Moss bags were exposed in parallel with and without irrigation for 3 and 6 months, respectively, at three different sites. Twenty-nine elements were determined in the exposed moss samples by INAA. For all exposure periods, higher uptake in the irrigated moss bags was evident for Al, Cr, Fe, Zn and Sr. Elements such as Cl, K, Rb and Cs were depleted in the moss tissue during the time of exposure. For most of the elements the accumulation after 6 months exceeded that observed after 3 months.     

Removal of doxycycline hydrochloride from aqueous solution by rice husk ash using response surface methodology and disposability study

Environmental Science and Pollution Research - The huge demand and consumption of DOX, its incomplete metabolism, and complex behavior in atmosphere are causing a great ecological issue, which...     

High consumption of pesticides in agricultural fields leads to prevalence of cancer cases in rural pockets of eastern India: A case study

This study was performed to evaluate the carcinogenic health risk of pesticides used in agricultural field in rural pockets of eastern India. The analysis of pesticide residue in rice grain sample was performed by Gas Chromatography Mass Spectrometry (GC-MS). It was observed that for pesticide DDT, the HR values was ranging between 0.5 to 3.2 and for lindane HR was 0.4 to 1.1, respectively. The DDT and Lindane exhibited HR values >1 in some sampling sites which revealed the carcinogenic effects and HR <1 in some sampling sites which revealed non carcinogenic effects of same pesticide. These results revealed a clear indication of potential carcinogenic health risk to human health through consumption of contaminated rice in some areas of Bargarh district. DDT has a long half-life, so it persists in the environment for a longer period of time and induces carcinogenic risk to human health predominantly than other pesticide lindane. A case study on cancer prevalence in Bargarh district was also carried out to support the findings of quantitative analysis. The primary data collected from the cancer affected area by personal questionnaires method to the person concern and the secondary data collected from the Bargarh District Head Quarters Hospital's register. The cancer death reported by the from the year 2015 to 2021 was 320, 380, 293, 323, 278, 409, 346 in the year of 2015, 2016, 2017, 2018, 2019, 2020, 2021 respectively, with the total number of 2349 cases. From the questionnaire data, it was observed that the occurrence of male and female cancer cases was 51.75% and 48.25%, respectively. Therefore, it was concluded that there was no significant difference in gender wise cancer prevalence. The most affected age group was 51–60, that is, 26.92% followed by 41–50, that is, 23.42%. Therefore, it was concluded that the middle-aged adults (40–60) were more vulnerable to the cancer than young adults (3–40) and old adults (60–100). The most prevalent cancer was breast (22.72%) followed by stomach (14.33%).